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Solar Cells
Solar cells (as the name implies) are designed to convert
(at least a portion of) available light into electrical
energy. They do this without the use of either chemical
reactions or moving parts.
History
The development of the solar cell stems from the work of
the French physicist Antoine-César Becquerel in 1839.
Becquerel discovered the photovoltaic
effect while experimenting with a solid electrode in an
electrolyte solution; he observed that voltage
developed when light fell upon the electrode. About 50 years
later, Charles Fritts constructed the first true solar cells
using junctions formed by coating the semiconductor
selenium with an ultrathin, nearly transparent layer of
gold. Fritts's devices were very inefficient, transforming
less than 1 percent of the absorbed light into electrical
energy.
By 1927 another metalÐsemiconductor-junction
solar cell, in this case made of copper and the semiconductor
copper oxide, had been demonstrated. By the 1930s both the
selenium cell and the copper oxide cell were being employed
in light-sensitive devices, such as photometers, for use in
photography. These early solar cells, however, still had
energy-conversion efficiencies of less than 1 percent. This
impasse was finally overcome with the development of the
silicon solar cell by Russell
Ohl in 1941. In 1954, three other American researchers,
G.L. Pearson, Daryl Chapin, and Calvin Fuller, demonstrated
a silicon solar cell capable of a 6-percent
energy-conversion efficiency when used in direct sunlight.
By the late 1980s silicon cells, as well as those made of
gallium arsenide, with efficiencies of more than 20 percent
had been fabricated. In 1989 a concentrator solar cell, a
type of device in which sunlight is concentrated onto the
cell surface by means of lenses, achieved an efficiency of
37 percent due to the increased intensity of the collected
energy. In general, solar cells of widely varying
efficiencies and cost are now available.
Structure
Modern solar cells are based on semiconductor
physics -- they are basically just P-N
junction photodiodes with
a very large light-sensitive area. The photovoltaic
effect, which causes the cell to convert light directly into
electrical energy, occurs in the three energy-conversion
layers.

Diagram courtesy U.S. Department of
Energy
The first of these three layers necessary for energy
conversion in a solar cell is the top junction layer (made
of N-type semiconductor
). The next layer in the structure is the core of the
device; this is the absorber layer (the P-N
junction). The last of the energy-conversion layers is
the back junction layer (made of P-type
semiconductor).
As may be seen in the above diagram, there are two
additional layers that must be present in a solar cell.
These are the electrical contact layers. There must
obviously be two such layers to allow electric current
to flow out of and into the cell. The electrical contact
layer on the face of the cell where light enters is
generally present in some grid pattern and is composed of a
good conductor such as a metal. The grid pattern does not
cover the entire face of the cell since grid materials,
though good electrical conductors, are generally not
transparent to light. Hence, the grid pattern must be widely
spaced to allow light to enter the solar cell but not to the
extent that the electrical contact layer will have
difficulty collecting the current produced by the cell. The
back electrical contact layer has no such diametrically
opposed restrictions. It need simply function as an
electrical contact and thus covers the entire back surface
of the cell structure. Because the back layer must be a very
good electrical conductor, it
is always made of metal.
Operation
Solar cells are characterized by a maximum Open Circuit
Voltage (Voc) at zero output
current and a Short Circuit
Current (Isc)
at zero output voltage. Since power can be computed via this
equation:
P = I * V
Then with one term at zero these conditions (V =
Voc / I = 0, V = 0 / I = Isc
) also represent zero power. As you might then expect, a
combination of less than maximum current
and voltage can be found that
maximizes the power produced (called, not surprisingly, the
"maximum power point"). Many BEAM
designs (and, in particular, solar
engines) attempt to stay at (or near) this point. The
tricky part is building a design that can find the maximum
power point regardless of lighting conditions.
For solar cell selection and comparison information, see
the solar
cell section of the BEAM
Reference Library's BEAM
Pieces collection. Also see the Starting
Block article
on solar cells.
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